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In recent years, thermal imaging and sensing technologies have seen dramatic increases in usage for a range of applications. However, the material cost and manufacturing complexity of infrared optics remain a major barrier toward their democratization. Here, a solution‐processed plasmonic reflective filter (PRF) is presented as a scalable, disordered, and low‐cost thermal infrared (TIR) optic. The PRF selectively absorbs sunlight and specularly reflects TIR wavelengths, with a performance comparable to state‐of‐the‐art infrared optics made of materials like Germanium. Unlike the latter, however, the PRF is fabricated using low‐cost materials and a “dip‐and‐dry” chemical synthesis technique, which enables orders of magnitude lower manufacturing costs. The PRF's optical functionality and integration into infrared imaging systems are experimentally demonstrated. The chemical synthesis technique also affords exceptional spectral tuneability and material compatibility compared to traditional fabrication methods. The PRF's tuneable and broadband TIR yield can be augmented by inexpensive dielectric or polymeric filters to yield novel capabilities such as wide‐area ambient temperature surveys. Practically, the PRF represents a significant advance toward democratizing the benefits of thermal imaging and sensing. Scientifically, it represents a previously unexplored optical functionality of disordered materials, and a new direction for versatile chemical synthesis in designing optical components. 

Abstract Passive daytime radiative cooling (PDRC) can realize electricity‐free cooling by reflecting sunlight and emitting heat to the cold space. Current PDRC designs often involve costly vacuum processing or a large quantity of harmful organic solvents. Aqueous and paint‐like processing is cost‐effective and environmentally benign, thereby highly attractive for green manufacturing of PDRC coatings. However, common polymers explored in PDRC are difficult to disperse in water, let alone forming porous structures for efficient cooling. Here, a simple “bottom‐up” ball milling approach to create uniform microassembly of poly(vinylidene fluoride‐co‐hexafluoropropene) nanoparticles is reported. The micro‐ and nanopores among secondary particles and primary particles substantially enhance light scattering and results in excellent PDRC performance. A high solar reflectance of 0.94 and high emittance of 0.97 are achieved, making the coating 3.3 and 1.7 °C cooler than commercial white paints and the ambient temperature, under a high solar flux of ≈1100 W m⁻². More importantly, the volatile organic compound content in the aqueous paint is only 71 g L⁻¹. This satisfies the general regulatory requirements, which are critical to sustainability and practical applications.